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A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

This paper reports results of an experimental investigation performed on a commercial diesel engine supplied with fuel blends having low cetane number to attain a simultaneous reduction in NOx and smoke emissions. Blends of 20% and 40% of n-butanol in conventional diesel fuel have been tested, comparing engine performance and emissions to diesel ones. Taking advantage of the fuel blend higher resistance to auto ignition, it was possible to extend the range in which a premixed combustion is achieved. This allowed to match the goal of a significant reduction in emissions without important penalties in fuel consumption. The experimental activity was carried on a turbocharged, water cooled, 4 cylinder common rail DI diesel engine. The engine equipment included an exhaust gas recirculation system controlled by an external driver, a piezo-quartz pressure transducer to detect the in-cylinder pressure signal and a current probe to acquire the energizing current to the injector.

Nitrous Oxide (N2O) is a greenhouse gas with a Global Warming Potential (GWP) of 298-310 [1,2] (298-310 times more potent than carbon dioxide (CO2)). As a result, any aftertreatment system that generates N2O must be well understood to be used effectively. Under low temperature conditions, N2O can be produced by Selective Catalytic Reduction (SCR) catalysts. The chemistry is reasonably well understood with N2O formed by the thermal decomposition of ammonium nitrate [3]. Ammonium nitrate and N2O form in oxides of nitrogen (NOx) gas mixtures that are high in nitrogen dioxide (NO2)[4]. This mechanism occurs at a relatively low temperature of about 200°C, and can be controlled by maintaining the nitric oxide (NO)/NO2 ratio above 1. However, N2O has also been observed at relatively high temperatures, in the region of 500°C.

Four-way, integrated, diesel emission control systems that combine selective catalytic reduction for NOx control with a continuously regenerating trap to remove diesel particulate matter were evaluated under real-world, on-road conditions. Tests were conducted using a semi-tractor with an emissions year 2000, 6-cylinder, 12 L, Volvo engine rated at 287 kW at 1800 rpm and 1964 N-m. The emission control system was certified for retrofit application on-highway trucks, model years 1994 through 2002, with 4-stroke, 186-373 kW (250-500 hp) heavy-duty diesel engines without exhaust gas recirculation. The evaluations were unique because the mobile laboratory platform enabled evaluation under real-world exhaust plume dilution conditions as opposed to laboratory dilution conditions. Real-time plume measurements for NOx, particle number concentration and size distribution were made and emission control performance was evaluated on-road.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

In this project funded by the Bayerische Forschungsstiftung two fundamental investigations had been carried out: first a new N-rich liquid ammonia precursor solution based on guanidine salts had been completely characterized and secondly a new type of side-flow reactor for the controlled catalytic decomposition of aqueous NH3 precursor to ammonia gas has been designed, applied and tested in a 3 liter passenger car diesel engine. Guanidine salts came into the focus due to the fact of a high nitrogen-content derivate of urea (figure 1). Specially guanidinium formate has shown extraordinary solubility in water (more than 6 kg per 1 liter water at room temperature) and therefore a possible high ammonia potential per liter solution compared to the classical 32.5% aqueous urea solution (AUS32) standardized in ISO 22241 and known as DEF (diesel emission fluid), ARLA32 or AdBlue®. Additionally a guanidine based formulation could be realized with high freezing stability down to almost ?30 °C (?

The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust.

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO3 (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn4+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/?-Al2O3 (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO2).

Cycle-to-cycle variations of combustion processes strongly affect the emissions, specific fuel consumption as well as work output. Especially Direct Injection Spark-Ignition (DISI) engines are very sensitive to cyclic fluctuations within the combustion chamber. Multi-cycle Large Eddy Simulation (LES) based analysis has been used for investigating unsteady effects of spray combustion processes and misfires. A realistic four-stroke DISI internal combustion engine configuration was taken under consideration. The effects of variable spray boundary conditions on spray combustion are discussed first. A qualitative analysis of the intensity of cycle-to-cycle variations of in-cylinder pressure is presented for various combinations of injection parameters and ignition points. Finally, the effect of ignition probability and analysis of misfires are pointed out. The described above processes were discussed in terms of mean and standard deviation of temperature, velocity and pressure.

What will the passenger car fleet look like over the next two decades? As most expected, affordability and convenience are the major drivers of new vehicle technology penetration into the market. Within this scope, vehicle electrification strategy to limit oil dependence and meet the European targets for CO2 emissions should be cost-effective and convenient to the buyer. This paper will focus first, through different economic models, on the penetration of passenger electrified vehicles (Plug-in Hybrid Vehicles PHVs and Electric Vehicles EVs) in Europe (EU15: 15 European Union member countries) up to 2030. Economic models are based on real world use behaviors and driving patterns in order to compute fuel and energy consumption and to estimate total cost of the vehicle including incentives. The economic models use household wages in order to later make conclusions on vehicle technology market shares by vehicle classes.

The Pennsylvania State University is one of 16 North American universities that participated in the EcoCAR advanced vehicle technology competition (http://www.ecocarchallenge.org/). A series-hybrid-electric vehicle based on a General Motors crossover SUV platform has been designed, built and tested for this purpose. The powertrain features a 1.3 L turbodiesel engine running on a B20 fuel system, a 75kW generator directly coupled to the engine and advanced lithium-ion batteries. In this paper, the vehicle architecture and control strategy are detailed and performance predictions (e.g., acceleration, fuel consumption and emissions) are presented. This includes discussion of the development process that led to the selected designs. The predicted performance is compared with data obtained on a chassis dynamometer and during on-road measurements over specified drive cycles. Presenter Shawn Getty

The Hybrid Electric Vehicle Team of Virginia Tech participated in the three-year EcoCAR Advanced Vehicle Technology Competition organized by Argonne National Laboratory, and sponsored by General Motors and the U.S. Department of Energy. The team established goals for the design of a plug-in, range-extended hybrid electric vehicle that meets or exceeds the competition requirements for EcoCAR. The challenge involved designing a crossover SUV powertrain to reduce fuel consumption, petroleum energy use, regulated tailpipe emissions, and well-to-wheel greenhouse gas emissions. To interface with and control the hybrid powertrain, the team added a Hybrid Vehicle Supervisory Controller, which enacts a torque split control strategy. This paper builds on an earlier paper [1] that evaluated the petroleum energy use, criteria tailpipe emissions, and greenhouse gas emissions of the Virginia Tech EcoCAR vehicle and control strategy from the 2nd year of the competition.

This paper presents a low-cost path for extending the range of small urban pure electric vehicles by hydraulic hybridization. Energy management strategies are investigated to improve the electric range, component efficiencies, as well as battery usable capacity. As a starting point, a rule-based control strategy is derived by analysis of synergistic effects of lead-acid batteries, high efficient operating region of DC motor and the hydraulic pump/motor. Then, Dynamic Programming (DP) is used as a benchmark to find the optimal control trajectories for DC motor and Hydraulic Pump/Motor. Implementable rules are derived by studying the optimal control trajectories from DP. With new improved rules implemented, simulation results show electric range improvement due to increased battery usable capacity and higher average DC motor operating efficiency. Presenter Xianke Lin

This paper presents a new concept for a 100% plastic prototype automotive door panel. This concept has the potential of providing a weight reduction of up to 40% compared to conventional steel door panels, but with equivalent performance (static strength). This innovative technology can be used for a variety of exterior automotive parts. The concept includes a composite sandwich panel combination of GFRP (glass fiber reinforced polymer), and LACTIF®, which is expanded beads foam made from PLA (polylactic acid) and developed by JSP Corporation. This GFRP+LACTIF® composite design offers the following characteristics: Excellent environmental resistance Strong adhesion Equivalent static strength (vs. conventional door panels) Design flexibility This concept also offers an alternative to conventional steel door panel systems by using unsaturated polyester material of plant origin as part of the GFRP composite.

Historically, studies by the National Highway Traffic Safety Administration (NHTSA) in support of CAF� rulemaking indicate that lightweighting vehicles lead to degraded safety. However, recent studies provided to NHTSA show that good designs for lightweighting can provide equivalent safety. This presentation highlights two studies funded by NHTSA in part to address these latest findings. The first is a George Washington University study, �Investigate Opportunities for Lightweighting Vehicles Using Advanced Plastics and Composites.� The second is an Electricore study, �Mass Reduction for Light-Duty Vehicles for Model Years 2017-2015. The findings presented include that it is possible to lightweight vehicles and provide equivalent safety and that costs drive designers toward the use of advanced metals.

Since 2006 Oak Ridge National Labs (ORNL) and the Pacific Northwest National Labs (PNNL) have conducted research of injection molded long glass fiber thermoplastic parts funded by U.S. DOE. At DOE's request, ACC's Plastics Division Automotive Team and USCAR formed a steering committee for the National Labs, whose purpose was to provide industry perspective, parts materials and guidance in processing. This ACC affiliation enabled the plastics industry to identify additional key research requirements necessary to the success of long glass fiber injection molded materials and their use in the real world. Through further cooperative agreements with Autodesk Moldflow and University of Illinois, a new process model to predict both fiber orientation distribution and fiber length distribution is now available. Mechanical property predictive tools were developed and Moldflow is integrating these models into their software.

In support of the U.S Department of Energy's Vehicle Technologies Program, numerous vehicle technology combinations have been simulated using Autonomie. Argonne National Laboratory (Argonne) designed and wrote the Autonomie modeling software to serve as a single tool that could be used to meet the requirements of automotive engineering throughout the development process, from modeling to control, offering the ability to quickly compare the performance and fuel efficiency of numerous powertrain configurations. For this study, a multitude of vehicle technology combinations were simulated for many different vehicles classes and configurations, which included conventional, power split hybrid electric vehicle (HEV), power split plug-in hybrid electric vehicle (PHEV), extended-range EV (E-REV)-capability PHEV, series fuel cell, and battery electric vehicle.

Software products in the automotive industry are by nature widely distributed and costly to update (recall), so high reliability is clearly of utmost importance. Just as clearly, the increasing reliance on remote access to such systems, for diagnostic and other purposes, has made security an essential requirement, and traditional techniques for software development are proving to be inadequate in dealing with these issues. Correctness by Construction is a software design and development methodology that builds reliability and security into the system from the start. It can be used to demonstrate, with mathematical rigor, a program's correctness properties while reducing the time spent during testing and debugging. This paper will discuss the use of Correctness by Construction, and its accompanying SPARK language technology, to improve automotive systems' security and reliability. (The approach can also account for safely issues, although that is not the focus of this paper.)

The first commercially available plug-in hybrid electric vehicle (PHEV), the General Motors (GM) Volt, was introduced into the market in mid-December 2010. The Volt uses a series-split powertrain architecture, which provides benefits over the series architecture that typically has been considered for use in electric-range extended vehicles (EREVs). A specialized EREV powertrain, called the Voltec, drives the Volt through its entire range of speed and acceleration with battery power alone and within the limit of battery energy, thereby displacing more fuel with electricity than a PHEV, which characteristically blends electric and engine power together during driving. This paper assesses the benefits and drawbacks of these two different plug-in hybrid electric architectures (series versus series-split) by comparing component sizes, system efficiency, and fuel consumption over urban and highway drive cycles.

This study undertakes an investigation of the effect of battery charge balance in hybrid electric vehicles (HEVs) on EPA fuel economy label values. EPA's updated method was fully implemented in 2011 and uses equations which weight the contributions of fuel consumption results from multiple dynamometer tests to synthesize city and highway estimates that reflect average U.S. driving patterns. For the US06 and UDDS cycles, the test results used in the computation come from individual phases within the overall certification driving cycles. This methodology causes additional complexities for hybrid vehicles, because although they are required to be charge-balanced over the course of a full drive cycle, they may have net charge or discharge within the individual phases. As a result, the fuel consumption value used in the label value calculation can be skewed.